338. Aluminum Ethoxide

Nomenclature

CAS number: 555-75-9
Ethanol aluminum salt (3:1); aluminum ethylate.
C6H15AlO3; mol wt 162.16.
C 44.44%, H 9.32%, Al 16.64%, O 29.60%.
Al(OC2H5)3.

Description and references

Prepd by reacting aluminum powder with absolute ethanol in xylene using small amounts of mercuric chloride and iodine as catalysts: Meerwein, Schmidt, Ann. 444, 232 (1925); Newer Methods of Preparative Organic Chemistry (Interscience, New York, 1948) p 132; see also Farbwerke vorm. Meister, Lucius und Brüning, DE 286596; J. Soc. Chem. Ind. London 34, 1168 (1915); Adkins, J. Am. Chem. Soc. 44, 2178 (1922). Laboratory procedure: Gattermann-Wieland, Praxis des Organischen Chemikers (de Gruyter, Berlin, 40th ed., 1961) p 333.

Properties

Liquid. bp6-8 200°; bp3 175-180°. Slowly solidifies to a whole white solid, mp 140°. May crystallize with alcohol of crystallization. Decomposed by water. Slightly sol in hot xylene, chlorobenzene, other high boiling solvents.

Use

In the reduction of aldehydes and ketones; as catalyst for polymerizations.