498. Ammonium Bifluoride

Nomenclature

CAS number: 1341-49-7
Ammonium fluoride ((NH4)(HF2)); acid ammonium fluoride; ammonium hydrogen fluoride.
F2H5N; mol wt 57.04.
F 66.61%, H 8.84%, N 24.56%.
NH4HF2.

Description and references

Prepn from hydrofluoric acid and NH3: Hassel, Luzanski, Z. Kristallogr. A83, 449 (1932); Gmelins, Ammonium (8th ed.) 23, 148 (1936).

Properties

Orthorhombic crystals which readily etch glass. d 1.5. mp 124.6°. Freely sol in water. Keep in plastic, rubber, wood or paraffined containers and well closed. See also Ammonium Fluoride.

Use

In manuf of Mg and Mg alloys; in brightening of Al; for purifying and cleansing various parts of beer-dispensing apparatus, tubes, etc., sterilizing dairy and other food equipment; in glass and porcelain industries; as mordant for aluminum; as a “sour” in laundering cloth. In lab production of HF.