523. Ammonium Formate

Nomenclature

CAS number: 540-69-2
Formic acid ammonium salt (1:1).
CH5NO2; mol wt 63.06.
C 19.05%, H 7.99%, N 22.21%, O 50.74%.
HCOONH4.

Description and references

Prepd from formic acid and NH3: Zuffanti, J. Am. Chem. Soc. 63, 3123 (1941); from methylformate and NH3: Kelly, Cuthbert, US 3122584 (1964 to Allied Chem.).

Properties

Deliquesc crystals or granules. d 1.27. mp 116°. Sol in less than its own wt of water; sol in alc. Keep tightly closed.

Use

In chemical analysis, especially to ppt base metals from salts of the “noble” metals.