806. Arsenic Trisulfide

Nomenclature

CAS number: 1303-33-9
Arsenic sulfide (As2S3); yellow arsenic sulfide; orpiment; auripigment; arsenic yellow; king's yellow; king's gold.
As2S3; mol wt 246.04.
As 60.90%, S 39.10%.

Description and references

The article of commerce contains much less sulfur than theory. Prepn: Gmelins, Arsenic (8th ed.) 17, pp 422-433 (1952).

Properties

Yellow or orange powder. mp reported from 300 to 325°. d 3.46. Practically insol in water. Sol in alkalies, alkali sulfides or carbonates; slowly sol in hot HCl; dec by HNO3.

Use

Manuf of glass, particularly infrared-transmitting glass; manuf of oil cloth, linoleum; in electrical semiconductors, photoconductors; as pigment; for depilating hides; in pyrotechnics.