Usually obtained by photochlorination of p-xylene: McBee et al., Ind. Eng. Chem. 39, 298 (1947); eidem in Slesser, Schram, Preparation, Properties, and Technology of Fluorine and Organic Fluoro Compounds (McGraw-Hill, New York, 1951) pp 207-221; Ross et al., J. Am. Chem. Soc. 75, 4697 (1953); Rabjohn, ibid. 76, 5479 (1954); Harvey et al., J. Appl. Chem. 4, 319 (1954); Ligett, US 2654789 (1953 to Ethyl Corp.).