1660. Calcium Chromate(VI)

Nomenclature

CAS number: 13765-19-0
Calcium chrome yellow; gelbin; yellow ultramarine; C.I. 77223; C.I. Pigment Yellow 33.
CaCrO4; mol wt 156.07.
Ca 25.68%, Cr 33.32%, O 41.01%.

Description and references

Prepn: Mylius, Wrochem, Ber. 33, 3689 (1900); Udy, US 2493789; US 2494215 (both 1950); Dunn, O'Brien, US 2745764/5 (both 1956 to Vanadium Corp. of America).

Properties

Yellow monoclinic or rhombic crystals. Sparingly sol in water; sol in dil acids; practically insol in alcohol. Also occurs as hemihydrate, monohydrate, and dihydrate.

Caution

Chromium hexavalent compounds are listed as known human carcinogens: Report on Carcinogens, Eleventh Edition (PB2005-104914, 2004) p III-63.

Use

As a pigment, corrosion inhibitor; manuf of chromium; in oxidizing reactions; in battery depolarization.