1712. Calcium Tungstate(VI)

Nomenclature

CAS number: 7790-75-2
CaO4W; mol wt 287.92.
Ca 13.92%, O 22.23%, W 63.85%.
CaWO4.

Description and references

Occurs in nature as the mineral scheelite. The article of commerce is usually made by pptn: Boericke, Boericke, US 2390687 (1945); prepn by heating a stoichiometric mixture of CaO or CaCO3 and tungstic acid: Kroger, Nature 159, 674 (1947); prepn of single crystals: Uitert, Soden, J. Appl. Phys. 31, 328 (1960).

Properties

Tetragonal crystals. d 6.06. Practically insol in water. Dec by hot HCl or HNO3.

Use

Very small crystals have been used for injection into malignant tumors, etc., thus affording by transillumination a means of x-ray treatment; for preparing screens for x-ray observations and photographs; in luminous paints; in scintillation counters.