1855. δ-Carotene

Nomenclature

CAS number: 472-92-4
ε,ψ-Carotene.
C40H56; mol wt 536.87.
C 89.49%, H 10.51%.

Description and references

Extracted from the fruit of Gonocaryum pyriforme Mig., Icacinaceae: Winterstein, Z. Physiol. Chem. 219, 249 (1933). Occurs also in carrots and certain varieties of tomatoes. Isoln from tomato mutants: Porter, Murphey, Arch. Biochem. Biophys. 32, 21 (1951). Structure: Kargl, Quackenbush, ibid. 88, 59 (1960). Synthesis: Manchand et al., J. Chem. Soc. 1965, 2019. Absolute configuration: Buchecker, Eugster, Helv. Chim. Acta 54, 327 (1971).

Chemical structure

Properties

Long orange-red needles from CS2 + hexane + ethanol, mp 140.5°. [α]Cd +317°; [α]D25 +352° ±16% (hexane). Absorption spectrum: Kargl, Quackenbush, loc. cit.