1898. Castor Oil

Nomenclature

Ricinus oil; oil of Palma Christi; tangantangan oil; Neoloid (Lederle).

Description and references

Fixed oil obtained by cold-pressing the seeds of Ricinus communis L., Euphorbiaceae. Triglyceride of fatty acids. Fatty acid composition is approx ricinoleic 87%, oleic 7%, linoleic 3%, palmitic 2%, stearic 1% and dihydroxystearic trace amounts: Binder et al., J. Am. Oil Chem. Soc. 39, 513 (1962). Review and bibliography: Anderson, J. Philipp. Pharm. Assoc. 42, 5-16 (1955); Dominguez et al., J. Chem. Educ. 20, 446 (1952); F. C. Naughton et al., in Kirk-Othmer Encyclopedia of Chemical Technology vol. 5 (Wiley-Interscience, New York, 3rd ed., 1979) pp 1-15.

Properties

Pale yellow, viscous oil. Slight somewhat characteristic odor. The crude oil tastes slightly acrid with a decidedly nauseating after-taste. Has excellent keeping qualities, does not turn rancid unless subjected to excessive heat. Dextrorotatory (undil. in sodium light). d15.515.5 0.961-0.963. Wt of tech grades: 8.1 to 8.9 lbs/gallon. nD25 1.473-1.477. nD40 1.466-1.473. Solidif -10° to -18°. Viscosity (25°): 6-8 P, also expressed as U ± 1/2 (Gardner-Holdt Scale). Flash pt 445°F (230°C); ignition temp 840°F (449°C). Surface tension (dynes/cm): at 20°, 39.0; at 80°, 35.2. Acid value <4. Sapon no. 176-187. Iodine no. (Wijs') 81-91. Reichert-Meissl value <0.5. Polenske value <0.5. Acetyl value 144-150. Hydroxyl value 161-169. Miscible with abs ethanol, methanol, ether, chloroform, glacial acetic acid. Dissolves in its own vol of petr ether or 95% alcohol. Does not dissolve to any extent in mineral oil, unless mixed with another vegetable oil. When heated to 300° for several hours it polymerizes and becomes miscible with mineral oil.

Use

As an industrial raw material for the prepn of chemical derivs used in coatings, urethane derivs, surfactants and dispersants, cosmetics, lubricants; chief raw material for the production of sebacic acid, a basic ingredient in the production of synthetic resins and fibers; as lubricant in metal drawing, machine lubrication and 2-cycle engine fuels, in hydraulic fluids, rubber preservative and mold lubricants; constituent of embalming fluids; in soap manuf; to impart emollient and lubricant properties to cosmetic prepns; as Turkey-red oil (sulfated castor oil) for dyeing and finishing textiles; as dehydrated castor oil in alkyds, resinous copolymers, varnishes, oil-based paints, enamels, calks and putties; as blown oil (oxidized oil) for plasticizing oilcloth, artificial leather, coated fabrics, and lacquers; to plasticize rosin in the manuf of sticky fly-paper, for nitrocellulose and similar coating systems, hot melts, duplicating and stencil inks, adhesives and laminants; as release and anti-sticking agent in hard candy manuf.

Therapeutic Category

Cathartic.

Therapeutic Category (Veterinary)

Mild purgative, but considered unreliable in adult horses. Emollient.

Keywords

Laxative/Cathartic