2445. Cobaltous Oxalate

Nomenclature

CAS number: 814-89-1
C2CoO4; mol wt 146.95.
C 16.35%, Co 40.10%, O 43.55%.
CoC2O4.

Description and references

Prepn: Robin, Bull. Soc. Chim. Fr. 1953, 1078; Gmelins, Cobalt (8th ed.) 58 (part A) p 355 (1932) and supplement, pp 704-706 (1961). Review: de Bie, Doyen, Cobalt 15, 3-13; 16, 3-15 (1962).

Properties

d425 3.021. Readily absorbs moisture from air to form hydrates.

Derivative

Dihydrate.

Properties

Light pink microcryst powder or needles. Almost insol in water; slightly sol in acids; almost insol in aq oxalic acid; freely sol in aq ammonia. Dec on heating with aq KOH or Na2CO3 soln.

Derivative

Tetrahydrate.

Properties

Yellowish-pink amorphous powder. Effloresces on exposure to air. Loses water on heating to 100° giving the dihydrate. Very slightly sol in water; slightly sol in acids; readily sol in aq ammonia.

Use

Prepn of Co catalysts, Co metal powder for powder-metallurgical applications; stabilizer for HCN; temperature indicator.