2449. Cobaltous Sulfide

Nomenclature

CAS number: 1317-42-6
CoS; mol wt 91.00.
Co 64.76%, S 35.24%.

Description and references

Prepn: Glemser in Handbook of Preparative Inorganic Chemistry vol. 2, G. Brauer, Ed. (Academic Press, New York, 2nd ed., 1965) p 1523.

Properties

Exists in two forms. α-CoS: black, amorphous powder. Forms Co(OH)S in air. Sol in HCl. β-CoS: grey powder or reddish-silver octahedral crystals. mp >1100°; d 5.45. Practically insol in water; sol in acids.

Use

Catalyst for hydrogenation or hydrodesulfurization.