2665. Cuprous Potassium Cyanide

Nomenclature

CAS number: 13682-73-0
Potassium bis(cyano-C)cuprate(1-); potassium dicyanocuprate(I); potassio-cuprous cyanide; potassium cyanocuprate(I).
C2CuKN2; mol wt 154.68.
C 15.53%, Cu 41.08%, K 25.28%, N 18.11%.
KCu(CN)2.

Description and references

Prepd by evaporation of an aq soln of CuCN and KCN: Staritzky, Walker, Anal. Chem. 28, 419 (1956).

Properties

Monoclinic, prismatic crystals. d 2.38. Practically insol in water; dec to CuCN by cold dil H2SO4 or heating in water; sol in DMSO.

Use

In electroplating copper and brass.