2875. 7-Dehydrositosterol

Nomenclature

CAS number: 521-04-0
(3β)-Stigmasta-5,7-dien-3-ol.
C29H48O; mol wt 412.69.
C 84.40%, H 11.72%, O 3.88%.

Description and references

From soy bean oil β-sitosterol: Wunderlich, Z. Physiol. Chem. 241, 116 (1936). Starting with cholesterol: US 2386635 (1945).

Chemical structure

Properties

Platelets from alc, browns on contact with air, mp 144-145°. [α]D21 -116° (c = 2 in chloroform). Sparingly sol in methanol, somewhat more in alcohol, freely sol in the other usual organic solvents. Insol in water.

Derivative

Acetate.
C31H50O2; mol wt 454.73.
C 81.88%, H 11.08%, O 7.04%.

Properties

mp 151-152°. [α]D21 -71° (c = 2 in chloroform).