Nomenclature
CAS number: 513-81-5
Diisopropenyl; β,γ-dimethyl-Δ-α,γ-butadiene.
C
6H
10; mol wt 82.14.
C 87.73%, H 12.27%.
Description and references
Occurs in the 66-70° fraction of Puertollano
shale oil. Prepd by slow distillation of anhydr pinacol in the presence
of hydrobromic acid: Allen, Bell, Org. Synth. coll. vol. III, 312; by rapid distillation of anhydr
pinacol over alumina at 420-470°: Newton, Coburn, ibid. 313.
Properties
Liquid. d2020 0.7273; d420 0.7267; d425 0.7222.
mp -76°. bp769 69.2°; bp760 68.8°. nD25 1.4362.Use
In the manuf of synthetic rubber and polymers.