3323. 1,1-Diphenylethene

Nomenclature

CAS number: 530-48-3
1,1′-Ethenylidenebisbenzene; unsym-diphenylethylene; α,α-diphenylethylene; α-methylene-diphenylmethane.
C14H12; mol wt 180.25.
C 93.29%, H 6.71%.

Description and references

Prepd by the action of phenylmagnesium bromide on ethyl acetate in ether, followed by treatment of the reaction product with ammonium chloride soln: Allen, Converse, Org. Synth. coll. vol. I (2nd ed., 1941) p 226. Absorption spectrum: Lardy, J. Chim. Phys. 21, 361 (1924).

Chemical structure

Properties

Liquid, mp 8.2°. d420 1.0232. bp760 277.0°; bp400 249.8°; bp200 222.8°; bp100 198.6°; bp60 183.4°; bp40 170.8°; bp20 151.8°; bp10 135.0°; bp5 119.6°; bp1.0 87.4°. nD20 1.60849.