Nomenclature
CAS number: 944-22-9
Ethylphosphonodithioic acid
O-ethyl
S-phenyl ester;
O-ethyl
S-phenyl ethylphosphonothiolothionate; N-2790; Dyfonate (Stauffer).
C
10H
15OPS
2; mol wt 246.33.
C 48.76%, H 6.14%, O 6.50%, P 12.57%, S 26.03%.
Description and references
Organophosphorus insecticide; cholinesterase
inhibitor. Prepn: Szabo et al., US 2988474 (1961 to Stauffer); H.
M. Pitt, R. A. Simone, DE 2002629; eidem, US 3642960 (1970, 1972 both to Stauffer). Toxicity and biochemistry of racemate and isomers: P.
W. Lee et al., Pestic. Biochem.
Physiol. 8, 146 (1978). Acute toxicity data:
R. Ben-Dyke et al., World Rev.
Pest Control 9, 119 (1970).
Properties
Light yellow liquid, bp0.1 130°. d2525 1.16. nD30 1.5883. Practically insol in water. Miscible with organic solvents.
LD50 in mice (mg/kg): 14.0 orally, 4.8 i.p. (Lee). LD50 in rats (mg/kg): 3-17 orally, 147 dermally (Ben-Dyke).Caution
Potential symptoms of overexposure
are nausea, vomiting, abdominal cramps, diarrhea, salivation; headache,
giddiness, vertigo, weakness; rhinorrhea, chest tightness; blurred
vision, miosis; cardiac irregularities; muscle fasciculations; dyspnea.
See NIOSH Pocket Guide to Chemical
Hazards (DHHS/NIOSH 97-140, 1997) p 146.Use
Soil insecticide.