4524. Gold Trioxide

Nomenclature

CAS number: 1303-58-8
Auric oxide; gold sesquioxide; gold oxide.
Au2O3; mol wt 441.93.
Au 89.14%, O 10.86%.

Description and references

Prepd from the hydroxide: Roseveare, Buehner, J. Am. Chem. Soc. 49, 1221 (1927).

Properties

Brown powder; begins to evolve oxygen at 110°; at 250° it is entirely dec to metallic gold; also slowly dec by sunlight. Practically insol in water. Sol in HCl, concd HNO3 and in NaCN soln. Keep protected from light.