5488. Lignoceric Acid

Nomenclature

CAS number: 557-59-5
Tetracosanoic acid.
C24H48O2; mol wt 368.64.
C 78.19%, H 13.12%, O 8.68%.
C23H47COOH.

Description and references

Obtained from beechwood tar or by the distillation of rotten oak wood: Sullivan, Ind. Eng. Chem. 8, 1027 (1916). Most natural fats contain small amounts (0.2-1%). The seed fat of the Indian tree Adenanthera pavonina is said to contain 25%. Synthesis: Fieser, Szmuszkovicz, J. Am. Chem. Soc. 70, 3352 (1948).

Properties

Crystals, mp 84.15°. nD100 1.4287. Soly in 91.53% ethanol: 0.182 g/100 ml. Neutralization value 152.2.

Derivative

Methyl ester.
C25H50O2; mol wt 382.66.
C 78.47%, H 13.17%, O 8.36%.

Properties

Platelets, mp 58-59.8°.