Nomenclature
CAS number: 16773-42-5
α-(Chloromethyl)-2-methyl-5-nitro-1
H-imidazole-1-ethanol; 1-(3-chloro-2-hydroxypropyl)-2-methyl-5-nitroimidazole; Ro-7-0207; Madelen (Finadiet); Ornidal (Selvi); Tiberal (Roche).
C
7H
10ClN
3O
3; mol wt 219.63.
C 38.28%, H 4.59%, Cl 16.14%, N 19.13%, O 21.85%.
Description and references
Prepn: NL 6606853; M. Hoffer, US 3435049 and US 3493582 (1966, 1969 and 1970, all
to Hoffmann-La Roche). Activity
studies: E. Grunberg et al., Proc.
Soc. Exp. Biol. Med. 133, 490 (1970). Synthesis
and antiprotozoal activity: M. Hoffer, E. Grunberg, J. Med. Chem. 17, 1019 (1974).
Pharmacokinetics: D. E. Schwartz, F. Jeunet, Chemotherapy 22, 19 (1976).
Properties
Crystals from toluene, mp 77-78°. uv max (2-propanol):
288, 312 nm (ε 3720, 9150). pKa: 2.4 ± 0.1. LD50 in rats, mice (mg/kg): 1780, 1420 orally (Grunberg). Also reported as LD50 in mice (mg/kg): >2000 orally, >2000 i.p. (Hoffer, Grunberg).Therapeutic Category
Anti-infective.
Keywords
Antiseptic/Disinfectant