7317. Phenyl Tolyl Ketone

C14H12O; mol wt 196.24.
C 85.69%, H 6.16%, O 8.15%.

Description and references

o-Isomer made from benzene and o-toluic acid chloride in the presence of AlCl3. p-Isomer made from benzoyl chloride and toluene in presence of AlCl3.

Chemical structure

Derivative

o-Phenyl tolyl ketone.

Nomenclature

(2-Methylphenyl)phenylmethanone; 2-methylbenzophenone.

Properties

Oily liquid. mp below -18°. bp 309-311°. Insol in water. Freely sol in alcohol, oils, most organic solvents.

Derivative

p-Phenyl tolyl ketone.

Nomenclature

(4-Methylphenyl)phenylmethanone; 4-methylbenzophenone.

Properties

Crystals, mp 59-60°. bp720 311-312°. Insol in water. Sol in alcohol; easily sol in benzene, ether, oils.

Use

As fixative in perfumery.