8180. Rhenium Trioxide

Nomenclature

CAS number: 1314-28-9
Rhenic anhydride.
O3Re; mol wt 234.21.
O 20.49%, Re 79.50%.
ReO3.

Description and references

Prepd by reduction of Re2O7 with dioxane: Nechamkin, Hiskey, Inorg. Synth. 3, 186 (1950); with CO: Melaven et al., ibid. 187.

Properties

Red cubic crystals; green luster by transmitted light; the color of the powder may appear blue (rhenium blue). At 400° disproportionates in vacuo to Re2O7 and ReO2. bp 750°. d 6.9-7.4. Practically insol in water, alkalies, non-oxidizing acids; oxidized by HNO3 to HReO4.