8741. Spermaceti

Nomenclature

Cetaceum; Spermwax (Robeco).

Description and references

A waxy substance from the head of the sperm whale. Constit. Chiefly cetyl palmitate; free cetyl alcohol present in appreciable amounts; esters of lauric, stearic, and myristic acids; esters of higher alcohols also present.

Properties

White, somewhat translucent, slightly unctuous masses with crystalline fracture and pearly luster; almost odorless and tasteless but becomes yellow and rancid on long exposure to air. d 0.938-0.944; mp 42-50°; nD80 ≈1.4330. Sapon no. 120-136. Iodine no. 3-4.4. Insol in water or cold alcohol. Sol in chloroform, ether, carbon disulfide, oils, boiling alcohol; slightly sol in petr ether.

Use

As a base for ointments, cerates, etc., and as emulsion with egg yolk or expressed almond oil. In manuf of candles, soaps, cosmetics, laundry wax; finishing and lustering linens. Emollient.