13-07045. Oxypinocamphone [Archived]
Nomenclature
CAS number: 10136-65-9
2-Hydroxy-2,6,6-trimethylbicyclo[3.1.1]heptan-3-one; 2-hydroxy-3-pinanone; 2-hydroxypinocamphone; Camphostene; Oxypinone. C10H16O2; mol wt 168.23.
C 71.39%, H 9.59%, O 19.02%.
Description and references
Prepn of l-form: Kuwata, J. Am. Chem. Soc. 59, 2509 (1937); Harispe et al., Bull. Soc. Chim. Fr. 1964, 1035; of dl-form: Kuwata, loc. cit. Stereochemistry: Carlson et al., Tetrahedron Lett. 1968, 5941.
Derivative
dl-Form.Properties
Crystals, mp 38.5-39.0°.Derivative
l-Form.Properties
Crystals from ether + petr ether, mp 35.5-36.5°. [α]D25 18.56° (c = 14.44 in alcohol).Therapeutic Category
Respiratory insufficiency.
Status
This monograph has been retired and is no longer subject to revision or update.