275. Negishi Cross Coupling
E. Negishi et al., J. Org. Chem. 42, 1821 (1977).
Formation of unsymmetric biaryls by cross coupling arylhalides with arylzinc reagents in presence of catalytic Ni or Pd:
References
Synthetic application: S. Superchi et al., Tetrahedron Lett. 37, 6057 (1996); J. A. Miller, R. P. Farrell, ibid. 39, 6441 (1998). Extension to additional functional groups: E. Negishi, Acc. Chem. Res. 15, 340 (1982). Review: P. Knochel, R. D. Singer, Chem. Rev. 93, 2117-2188 (1993); idem et al., Ber. 130, 1021-1027 (1997).