513. Ammonium Cobaltous Phosphate

Nomenclature

CAS number: 14590-13-7
Phosphoric acid ammonium cobalt(2+) salt (1:1:1); cobaltous ammonium phosphate.
CoH4NO4P; mol wt 171.94.
Co 34.28%, H 2.34%, N 8.15%, O 37.22%, P 18.01%.
NH4CoPO4.

Description and references

Prepd by reaction of a cobaltous salt with (NH4)3PO4, (NH4)2HPO4, or H3PO4 and NH3: Grat-Cabanac, Bull. Microsc. Appl. 8, 97 (1958); Salutsky et al.; McCullogh, Salutsky, US 3126254; US 3141732 (both 1964 to W. R. Grace).

Properties

Hydrate, red to violet powder, or monoclinic rectangular lamellae. Practically insol in water. Sol in acids.

Use

As pigment in ceramic glazes and vitreous enamels; as temp indicator in textile industry; in fertilizers for plant nutrition; in Co analysis.