Nomenclature
CAS number: 497-18-7
Carbonic dihydrazide; 1,3-diaminourea.
CH
6N
4O; mol wt 90.08.
C 13.33%, H 6.71%, N 62.20%, O 17.76%.
Description and references
Prepd by refluxing diethyl carbonate with hydrazine
hydrate: Mohr et al., Inorg. Synth. 4, 32 (1953).
Properties
Crystals from water + ethanol, dec 153-154°.
Freely sol in water. pH of 1% aq soln ≈7.4. Practically insol in
alcohol, ether, chloroform, benzene. Forms salts with acids. With nitrous acid it forms the highly explosive carbonyl
azide CO(N3)2.