Nomenclature
CAS number: 511-34-2
(2α,3β,5α,15β,25
R)-Spirostan-2,3,15-triol.
C
27H
44O
5; mol wt 448.64.
C 72.28%, H 9.89%, O 17.83%.
Description and references
The aglycon of digitonin: Tschesche, Ber. 68, 1090 (1935); Tschesche,
Hagedorn, Ber. 69, 797
(1936). Structure and stereochemistry: Marker et al., J. Am. Chem. Soc. 64, 1843 (1942); Meystre et al., Helv. Chim. Acta 38, 381 (1955). Klass et al., J. Am. Chem. Soc. 77, 3829 (1955); and IR spectra: Djerassi et al., ibid. 78, 3166 (1956).
Properties
Needles from alc, dec 296°. [α]D19 -81° (c
= 1.4 in chloroform). Practically insol in water. Sol in 30
parts chloroform, 35 parts boiling alc, 100 parts alc at 20°.Derivative
2,3-Diacetate.
Properties
Crystals from methanol-chloroform, mp 241.5-242°. [α]D -104°.Derivative
Triacetate.
Properties
Minute needles from ether, mp 190°.