5095. Irone

Nomenclature

CAS number: 1335-94-0
6-Methylionone.

Description and references

The fragrant principle of violets, best isolated from the rhizomes of iris or from orris oil: F. Tiemann, P. Kruger, Ber. 26, 2675 (1893); Ruzicka et al., Helv. Chim. Acta 16, 1143 (1933); Naves, Mazuyer, Les Parfums Naturels (Paris, 1939). Irone, as isolated, is an isomeric mixture of α-, β, and γ-irones, q.q.v., with each having the same molecular formula, C14H22O . Synthesis of isomeric mixture: Eschinazi, US 3019265 (1962 to Givaudan).

Properties

Light yellow, slightly viscous liquid. Very stable, does not discolor. In dil alcoholic soln the characteristic odor of violets is best appreciated.

Use

In perfumery for orris and violet compositions.