8850. Strontium Titanate

Nomenclature

CAS number: 12060-59-2
Strontium titanium oxide (SrTiO3).
O3SrTi; mol wt 183.49.
O 26.16%, Sr 47.75%, Ti 26.09%.
SrTiO3.

Description and references

Dielectric and photoelectric material. Occurs in nature as the mineral tausonite. Optical properties: H. A. Weakliem et al., RCA Rev. 36, 149 (1975). Electrical conductivity: U. Balachandran, N. G. Eror, J. Solid State Chem. 39, 351 (1981). Dielectric properties of glass-ceramics: S. L. Swartz, A. S. Bhalla, Ferroelectrics 87, 141 (1988). Review of growth and properties of single crystals: K. Nassau, A. E. Miller, J. Cryst. Growth 91, 373-381 (1988). Prepn by sol-gel method: J. Moreno et al., J. Mater. Chem. 5, 509 (1995); by solution-precipitation method: V. Kumar, J. Am. Ceram. Soc. 82, 2580 (1999). Prepn of thin films by ECR plasma sputtering: S. Miyake et al., Surf. Coat. Technol. 169-170, 27 (2003); by spray pyrolysis: G. Brankovic et al., J. Eur. Ceram. Soc. 24, 989 (2004). Piezoelectric response at cryogenic temperatures: D. E. Grupp, A. M. Goldman, Science 276, 392 (1997). IR characterization of thin films: B. G. Almeida et al., Appl. Surf. Sci. 238, 395 (2004). Room-temperature ferroelectricity: J. H. Haeni et al., Nature 430, 758 (2004).

Properties

d 5.12. nD 2.409. Hardness 5 on Moh's scale. Specific heat: ≈10 J s-1 K-1 m-1. Thermal conductivity: ≈52 mW cm-1 K-1.

Use

In electronics and electrochemical insulation; in photocatalysis; sputtering target for thin film capacitors; substrate for epitaxial growth of high temperature superconductor thin films. Diamond simulant gemstone.