Nomenclature
CAS number: 80-69-3
2-Hydroxypropanedioic acid; hydroxymalonic acid.
C
3H
4O
5; mol wt 120.06.
C 30.01%, H 3.36%, O 66.63%.
Description and references
Prepd by ozonization of malonic acid in aq
soln: Dobinson, Chem. Ind. (London) 1959, 853.
Properties
Colorless, odorless crystals. Crystallizes from
water with and 1H2O. Becomes anhydr at 60°. Sublimes
110-120°. mp 158-160° with decompn (CO2 evolved). pK1 2.42; pK2 4.54, see Grandjean, Bull. Soc. R. Sci. Liege 38, 288
(1969), C.A. 72, 42684t
(1970). Very sol in water, alcohol; the anhydrous acid is sol in
ether.