Nomenclature
CAS number: 131-79-3
1-[(2-Methylphenyl)azo]-2-naphthalenamine; C.I. Solvent Yellow 6; 1-
o-tolylazo-2-naphthylamine; FD & C Yellow no. 4; Ext. D & C Yellow no. 10; C.I. 11390.
C
17H
15N
3; mol wt 261.32.
C 78.13%, H 5.79%, N 16.08%.
Description and references
Prepd from diazotized o-toluidine
and β-naphthylamine: Krüss, Z. Phys. Chem. 51, 270 (1905); Norman, J. Chem.
Soc. 101, 1913 (1912); Fischer, J. Prakt. Chem. 104, 102 (1922);
Hodgson, Foster, J. Chem. Soc. 1942, 30. Toxicity studies: Allmark et al., J. Pharm. Pharmacol. 7, 591 (1955); Hansen et al., Toxicol.
Appl. Pharmacol. 5, 16 (1963). Formerly used
in the U.S. for coloring oleomargarine.
Properties
Deep red crystals from alc. Also reported as
bright yellow needles (Krüss). mp 125-126° (Fischer). Practically insol in water. Sol
in alc, ether, benzene, carbon tetrachloride, vegetable oils, glacial
acetic acid. An alcoholic soln becomes redder with HCl addition,
but is unaltered by NaOH addition.