13-06952. Oryzacidin [Archived]

Nomenclature

CAS number: 1400-67-5

Description and references

Antibiotic substance produced by a strain of Aspergillus oryzae: Shimoda, J. Agric. Chem. Soc. Jpn. 25, 254 (1951), C.A. 46, 10284 (1952); idem, JP 52 1594 (1952), C.A. 47, 6097 (1953). Production of oryzacidin A by Streptomyces: idem, JP 65 13198 (1965), C.A. 63, 12284c (1965).

Properties

Hygroscopic needles, dec 162-163°. [α]D13.5 133°. Sol in water, methanol, ethanol, isopropanol, hot acetone. Slightly sol in butanol, ethyl acetate. Practically insol in ether, acetone, chloroform, carbon tetrachloride.

Derivative

Quinine salt.

Properties

Tabular crystals, dec 210°.

Derivative

Oryzacidin A.

Properties

Orange, amorphous powder, mp 231°. Soluble in ether, benzene, carbon tetrachloride, methanol, ethanol, butyl acetate, chloroform, pyridine, dioxane, acetic acid, toluene, xylene. Slightly sol or insol in water, acetone, carbon disulfide, isopropyl ether, petr ether, hexane. pH of ethanolic soln, 6.6. uv max: 243 nm (E1%1cm 122.5). Stable in direct sunlight.

Status

This monograph has been retired and is no longer subject to revision or update.