2722. Cycloheptanone

Nomenclature

CAS number: 502-42-1
Suberone; ketoheptamethylene; ketocycloheptane.
C7H12O; mol wt 112.17.
C 74.95%, H 10.78%, O 14.26%.

Description and references

Prepn from cyclohexanol with 1-(aminomethyl)cyclohexanol as the intermediate: Blicke et al., J. Am. Chem. Soc. 74, 2924 (1952). Other methods: Org. Synth. coll. vol. IV, 221-228 (1963).

Chemical structure

Properties

Liquid. d420 0.9490. bp760 179-181°. bp16 66-70°. nD20 1.4608. Dipole moment 2.98. Practically insol in water. Freely sol in alcohol. Sol in ether.

Derivative

Oxime.

Nomenclature

Suberoxime.
C7H13NO; mol wt 127.18.
C 66.11%, H 10.30%, N 11.01%, O 12.58%.

Properties

mp 23°, bp20 152°.