4045. Ferrous Fluoride

Nomenclature

CAS number: 7789-28-8
F2Fe; mol wt 93.84.
F 40.49%, Fe 59.51%.
FeF2.

Description and references

Prepn from FeCl2 and HF gas: Kwasnik in Handbook of Preparative Inorganic Chemistry, G. Brauer, Ed. (Academic Press, New York, 2nd ed., 1963) p 266; from Fe powder and liq HF: Muetterties, Castle, J. Inorg. Nucl. Chem. 18, 148 (1961).

Properties

Tetragonal crystals (rutile type) or powder. Sublimes at about 1100°. d 4.09. Sparingly sol in water; more sol in dil HF. Practically insol in alcohol, ether, benzene.

Use

As catalyst in organic reactions.